Chemically treated Borneo sago (Metroxylon sagu) starch reinforced poly lactic acid bio-composites

Author:

Rahman Md. Rezaur1,Hamdan Sinin1,Baini Rubiyah Binti1,Bakri Muhammad Khusairy Bin1,Adamu Muhammad2,Nyuk Khui Perry Law1,Kakar Akshay3,Sanaullah Khairuddin4

Affiliation:

1. Universiti Malaysia Sarawak

2. Universiti Malaysia Sarawak; Nigerian National Petroleum Corporation

3. University of Houston

4. Ton Duc Thang University;

Abstract

Properties of Borneo sago starch reinforced poly-(lactic acid) (PLA) composites were evaluated, with attention to the effects of treatment with acrylic acid, benzene diazonium chloride, and tetrahydrofuran. The PLA-sago composites treated with tetrahydrofuran had the highest tensile strength, with a maximum value of 0.85 MPa at 20 wt%; whereas the PLA-sago composites treated with benzene diazonium chloride had the highest modulus of elasticity, with a maximum modulus of elasticity of 28 kPa at 5 wt%. Scanning electron microscopy images of the surfaces showed good interfacial contact between the PLA and the sago starch treated with benzene diazonium chloride. The Fourier-transform infrared spectra revealed the functional group characteristics of the chemicals composition of the materials. According to the thermogravimetric analysis results, all of the composites displayed thermal stability up to a temperature of 300 °C. The differential scanning calorimetry analysis revealed that the poly lactic acid-sago composites treated with benzene diazonium chloride had the highest melting point.

Publisher

BioResources

Subject

Waste Management and Disposal,Bioengineering,Environmental Engineering

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