Progress in the synthesis and properties of 2,5-furan dicarboxylate based polyesters

Abstract

Biomass is a class of abundant renewable resource. Its efficient use in the field of biobased materials is one of the important ways for implementation of sustainable development strategies. 2,5-Furandicarboxylic acid (FDCA) as a potential alternative of terephthalic acid (PTA) to make alipharomatic polyesters, can be obtained in mass amount from cellulose via bio- or chemical process. For this reason, FDCA-based polyesters have gained high interest recently. This review systematically summarizes recent progress in the making of FDCA-based polyesters (including poly(ethylene 2,5-furandicarboxylate) (PEF), poly(propylene 2,5-furandicarboxylate) (PPF), poly(butylene 2,5-furandicarboxylate) (PBF), poly(hexylene 2,5-furandicarboxylate) (PHF), and their copolyesters), especially highlighting the progress and fundamental aspects for their synthesis and properties. Significant advantages (and also disadvantages) of the FDCA-based polyesters are clearly indicated relative to price, performance, and sustainable development, in reference to traditional petroleum-based polyesters in industrial application. The goal of this review is to provide useful information regarding the synthesis and properties of FDCA-based polyesters.