MIL-53(Fe)@γ-Al2O3 nanocomposites incorporated cellulose acetate for forward osmosis membranes of high desalination performance

Author:

Li Tong,Ba Xuelian,Wang XiujuORCID,Wang Zhongpeng,Yang Jie,Cui Yu,Wang LiguoORCID

Abstract

Forward osmosis (FO) membrane is a promising membrane technique. However, its application in desalination is limited. Thus, we synthesized MIL-53(Fe)@γ-Al2O3 via solvent-thermal method to fabricate MIL-53(Fe)@γ-Al2O3/cellulose acetate (CA) composite membranes of high desalination performance. MIL-53(Fe)@γ-Al2O3 and MIL-53(Fe) particles were studied using XRD, FITR, SEM, N2 adsorption-desorption isotherms, and AFM. The structural features of MIL-53(Fe)@γ-Al2O3/CA membrane and MIL-53(Fe)/CA membrane were analyzed using SEM, AFM and water contact angle. The reverse salt flux and water flux of the MIL-53(Fe)@γ-Al2O3/CA membrane reached 1.78 g m-2 h-1 and 37.1 L m-2 h-1, respectively, when the deionized water and 1 M NaCl solution were the feed solution and traction solution, respectively. Compared to the MIL-53(Fe)/CA membrane, the MIL-53(Fe)@γ-Al2O3/CA membrane demonstrated better perviousness and selectivity properties of the membrane. This study shows a potential advantage of MOF composites as additives for improvement in the desalination performance of forward osmosis membranes.

Funder

Shandong Province Natural Science Foundation

Shandong Key Laboratory of Water Pollution Control and Resource Reuse

Shandong Province Key Research and Development Plan

National Natural Science Foundation of China

Project of Shandong Province Higher Educational Science and Technology Program

Publisher

Korean Society of Environmental Engineering

Subject

Environmental Engineering

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