Development and validation of freshwater sediment quality assessment guidelines for trace elements in Korea

Abstract

Sediment quality assessment guidelines(SQAGs) for seven trace elements were suggested to build an assessment system of freshwater sediment quality for a regulatory program in Korea. In this study, current one-step SQAGs were divided into three levels based on the probability of toxicity occurrence, namely, the threshold-effect-level(TEL), the probable-effect-level(PEL), and the apparent-effect-threshold(AET). A sediment toxicity database consisting of field-collected sediments and toxicity results from three different species were used to derive TEL, PEL, and AET. The ambient background concentrations of trace elements in freshwater sediments were used instead of the TEL values because TEL values were lower than the ambient background levels. To validate the reliability of the new SQAGs, a separate sediment toxicity database based on G. sobaegensis was used. When the mean quotient value for the PEL was 0.34, the reliability reached a maximum of 87% with a positive predictive value of 94% and a negative predictive value of 85%. These results showed the newly derived SQAGs were very useful for assessing and predicting the toxicity of field sediments in Korea. Finally, ambient background concentrations, a mean quotient of PEL of 0.34, and AETs were used to classify the quality of the field-collected sediments into four categories.