Optimizing quantum dot solar cells: exploring defect density effects with PTAA HTL layer simulation using SCAPS-1D

Author:

Umar Ahmad1,Yadav Vaishali2,Srivastava Vaibhava2,Sadanand 3,Lohia Pooja2,Dwivedi Dilip Kumar4,Ibrahim Ahmed A5,Akbar Sheikh6,Qasem Hussam7,Baskoutas Sotirios8

Affiliation:

1. Department of Chemistry, Faculty of Science and Arts and Promising Centre for Sensors and Electronic Devices, Najran University, Najran, Kingdom of Saudi Arabia; Department of Materials Science and Engineering, Ohio State University, Columbus, OH, USA

2. Department of Electronic and Communication Engineering, Madan Mohan Malaviya University of Technology, Gorakhpur, India

3. Department of Applied Sciences, Galgotias College of Engineering and Technology, Greater Noida, India

4. Photonics and Photovoltaic Research Lab, Madan Mohan Malaviya University of Technology, Gorakhpur, India

5. Department of Chemistry, Faculty of Science and Arts and Promising Centre for Sensors and Electronic Devices, Najran University, Najran, Kingdom of Saudi Arabia

6. Department of Materials Science and Engineering, Ohio State University, Columbus, OH, USA

7. National Centre for Renewable Energy, King Abdulaziz City for Science and Technology, Riyadh, Kingdom of Saudi Arabia

8. Department of Materials Science, University of Patras, Patras, Greece

Abstract

In recent years, quantum dot solar cells have attracted attention due to their versatile electrical and optical properties as a material. A quantum dot solar cell can be tuned in terms of bandgap and size. In this work, the effect of defect density on the performance of a solar cell is studied with the help of the Solar Cell Capacitance Simulator in One Dimension (SCAPS-1D) software. The defect densities of poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA)/lead sulfide (PbS)–tetrabutylammonium iodide (TBAI) and lead sulfide–TBAI/titanium dioxide (TiO2) are varied from 1 × 1010 to 1 × 1017 cm−2, and the electron mobility of titanium dioxide, temperature and work function are also varied. These simulation-based quantum dot absorber-based solar cells may, in the future, prove to be extremely effective quantum dot solar cells.

Publisher

Thomas Telford Ltd.

Subject

Condensed Matter Physics,General Materials Science

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