Acoustic behaviour of Portland cement paste with sodium gluconate additive during hydration

Abstract

The ultrasonic pitch–catch method was used to study the hydration behaviour of Portland cement paste with sodium gluconate (SG) additive using a tailor-made piezoelectric transducer. X-ray diffraction analysis showed that the intensity of the diffraction peak of calcium hydroxide decreased with increasing SG content (CSG), especially for CSG > 0.10 wt%. The compressive strength of the hardening cement pastes decreased remarkably for the pastes with CSG > 0.05 wt%. Ultrasonic waveforms appeared after 2 h of hydration and the waveform amplitudes of cement pastes with SG contents of 0.15 wt% and 0.20 wt% were obviously larger than those of cement pastes with CSG = 0.05 wt% in the early hydration stage. The hydration process of the cement paste over 300 h was classified into three stages based on the head wave amplitude variation – the fluctuation period, the rapidly increasing period and the smoothly increasing period. The acoustic propagation time changed greatly with hydration before a hydration age of 48 h, indicating that the hydration and hardening process of the cement paste was intense in the first 48 h. The proposed ultrasonic monitoring method opens a new perspective for studying the hydration behaviour of SG-blended cement paste.