Corrosion prediction models for steel bars in chloride-contaminated concrete: a review

Abstract

Concern has been expressed in the recent decades about the corrosion prediction of concrete structures in a chloride environment. This paper summarises the corrosion prediction models developed for chloride-contaminated concrete, including both the empirical and electrochemical corrosion models. The definition methods of the steel de-passivation process for electrochemical models, such as anode–cathode ratio (Aa/Ac), critical chloride concentration (CCl,crit), modification of anodic Tafel slope (βa) or passive film resistance (Rf), are considered essential and discussed in detail. Furthermore, electrochemical parameters regarding the definition and selection in electrochemical models and experimental measurements are discussed. This study confirms that Aa/Ac and CCl,crit have been generally used in recent years, and that the modifications of βa and Rf related to free chloride concentration are technically feasible. In addition, the discreteness of electrochemical parameters in electrochemical models and experimental measurements are observed, and time-dependent characteristics of electrochemical parameters are scarcely presented in the existing literature.