Hysteretic water-retention behaviour of unsaturated hydrophobised soils

Abstract

Hydrophobised soils found in the superficial region of earthen infrastructure can affect the hydrological processes of these structures. The hysteretic water-retention curve (WRC), which governs these processes, for hydrophobised soils has rarely been reported. Existing apparatus is unable to measure the WRC of unsaturated soils as it could not control the condition of pore water pressure (uw) in excess of pore air pressure (ua) when the contact angle was larger than 90°. In this study, a new apparatus was created, which sandwiches a soil sample between a high water-entry value (WEV) membrane and a high air-entry value (AEV) ceramic disc, to control the uw < ua and uw > ua conditions. Contact angle hysteresis and menisci evolution in the test materials during wet–dry cycles were measured to interpret the WRC. The WEV of soil increased with decreasing chemical heterogeneity and particle size. When drying the hydrophobised soils, they could retain water before reaching a certain negative uw. The WEV identified from the second wetting cycle was lower than that from the first cycle, whereas the AEV remained largely unchanged. The WEV and AEV decreased when the particle size of the hydrophobised materials was increased, resulting in a smaller hysteresis size.