Intensity Enhancement of a Two-Dimensional Asynchronous Spectrum Without Noise Level Fluctuation Escalation Using a One-Dimensional Spectra Sequence Change

Author:

Li Kaili12,Zhou Fengshan1,He Anqi23,Guo Ran24,Li Xiaopei5,Xu Yizhuang24ORCID,Noda Isao26ORCID,Ozaki Yukihiro27,Wu Jinguang2

Affiliation:

1. Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing, China

2. Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing, China

3. College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, China

4. Jiangsu JITRI Molecular Engineering Inst. Co., Ltd, Suzhou, China

5. Instrumental Analysis Center, Dalian Polytechnic University, Dalian, China

6. Department of Materials Science and Engineering, University of Delaware, Newark, DE, USA

7. Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Hyogo, Japan

Abstract

Previously, we demonstrated that the intensities of cross-peaks in a two-dimensional asynchronous spectrum could be enhanced using sequence change of the corresponding one-dimensional spectra. This unusual approach becomes useful when the determination of the sequential order of physicochemical events is not essential. However, it was not known whether the level of noise in the two-dimensional asynchronous spectrum was also escalated as the sequence of one-dimensional spectra changed. We first investigated the noise behavior in a two-dimensional asynchronous spectrum upon changing the sequence of the corresponding one-dimensional spectra on a model system. In the model system, bilinear data from a chromatographic–spectroscopic experiment on a mixture containing two components were analyzed using a two-dimensional asynchronous spectrum. The computer simulation results confirm that the cross-peak intensities in the resultant a two-dimensional asynchronous spectrum were indeed enhanced by more than 100 times as the sequence of one-dimensional spectra changed, whereas the fluctuation level of noise, reflected by the standard deviation of the value of a two-dimensional asynchronous spectrum at a given point, was almost invariant. Further analysis on the model system demonstrated that the special mathematical property of the Hilbert–Noda matrix (the modules of all column vectors of the Hilbert–Noda matrix being a near constant) accounts for the moderate variation of the noise level during the changes of the sequence of one-dimensional spectra. Next, a realistic example from a thermogravimetry–Fourier transform infrared spectroscopy experiment with added artificial noise in seven one-dimensional spectra was studied. As we altered the sequence of the seven FT-IR spectra, the variation of the cross-peak intensities covered four orders of magnitude in the two-dimensional asynchronous spectra. In contrast, the fluctuation of noise in the two-dimensional asynchronous spectra was within two times. The above results clearly demonstrate that a change in the sequence of one-dimensional spectra is an effective way to improve the signal-to-noise level of the two-dimensional asynchronous spectra.

Funder

National Natural Science Foundation of China

Innovation of Instrumentation and Key Techniques Foundation of Peking University

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Cited by 7 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3