Raman and Energy Dispersive Spectroscopy (EDS) Analyses of a Microsubstance Adhering to a Fiber of the Turin Shroud

Author:

Laude Jean-Pierre1,Fanti Giulio

Affiliation:

1. Department of Industrial Engineering, Padua University, Italy

Abstract

The Raman spectrum of a microsubstance, smeared on a fiber coming from the Shroud of Turin, was compared with numerous spectra published for old or modern pigment dyes, whole bloods, dried bloods, red blood cells, albumin, very ancient blood stains, and various “degradation” products of heme. Within the wavenumber measure accuracy, it is shown that all Raman lines detected above background could correspond to vibration frequencies found in biliverdin-derived compounds except a weak line that we tentatively attributed to amide I. Biliverdin is known as an oxidative ring cleavage product of the heme of blood. Energy dispersive spectroscopy (EDS) analysis of the sample confirms an elemental composition fully compatible with this hypothesis. Therefore, it is very likely that this microsubstance contains products of heme including heme/biliverdin-derived compounds and protein traces (amide I). Nevertheless, other measures will be necessary to confirm it. This method of identification, adding EDS to Raman spectrometry can be applied to nondestructive testing (NDT) of many other microsamples.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Reference42 articles.

1. Molecular Spectroscopy

2. The Shroud of Turin: blood or artist's pigment?

3. Bouchard-Abouchacra M. “Evaluation des capacités de la microscopie Raman dans la Characterisation minéralogique et physico-chimique des matériaux archéologiques: Métaux vitraux et pigments”, Thèse. Paris: Muséum National d'Histoire Naturelle, 2001, pp. 1–358.

4. Le rouge est mis1: analyse des rouges dans la faïence de « grand feu » du xviiie et du xixesiècle (avec le rouge de Thivie

Cited by 5 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3