Exploration of Curing Characteristics of Epoxy-Modified Asphalt

Abstract

A study was conducted on epoxy-modified asphalt (EMA) diluted with two binders of a different chemical structure, to understand the effect of curing rates and long-term postcuring characteristics. Dynamic shear rheometer test results did not show a clear trend of curing time and dosage percentage impact for the two base binders; parallel-plate geometry may not be well-suited to study EMA because of the thermosetting properties of curing. The asphalt binder test (ABT) method was used to assess the effect on rheology of short-term and long-term curing. Analysis of the ABT data to date suggests that the binder source has a notable effect on the composite properties. The impact of long-term storage was also found to be dependent on the asphalt binder used. Findings from this study were also applied to two field binders; one was modified using styrene-butadiene-styrene polymer, and the other contained epoxy. Curing times were determined using the ABT test. The Dongre Workability Test (DWT) was also conducted on open-graded friction course mixes and the mix curing times were found to be significantly higher than those determined on the binders. A method based on DWT data to determine a “workability window” was also explored. The Strategic Highway Research Program (SHRP) sol-type binder AAG-2 was found to exhibit little to no reactivity with the epoxy modifier used in this study. The SHRP gel-type binder AAD-2, however, was found to be highly reactive. The short-term curing temperature was found to affect the rate of curing for base binder AAD-2. The curing rate was found to be highest at 165°C followed by 120°C, and the rate was at its slowest at 25°C. AAG-2 did not show any onset of curing at either temperature.