Synthesis and Characterization of Polystyrene Core/Polyacrolein Shell Latexes

Abstract

The poly(styrene/acrolein) latexes were synthesized in an emul sifier-free emulsion-precipitation polymerization. Monodisperse particles from 0.30 μm to 0.52 μm, depending on the acrolein monomer feed, were obtained. More acrolein in the monomer feed yielded latex particles with smaller di ameters. Analyses indicate that the particles have a core-shell morphology. The core is rich in the hydrophobic (polystyrene) component whereas the shell is composed mainly of hydrophilic polyacrolein. Significant changes in polyacro lein in the latexes (from 0.03 to 0.28) has less influence on the composition of the shell (from 0.5 to 0.84, respectively). The surface of the latex particles is smooth and can be penetrated by 2,4-dinitrophenyl hydrazine to the depth from 1.5 to 3.5 Å. These poly(styrene/acrolein) latexes are capable of binding ca. 3 mg of human globulins or ca. 1 mg of human serum albumin on 1 m2 of the latex surface.