Affiliation:
1. State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, Beijing, China
2. Research and Development Department, Xining Special Steel Group, Co., Ltd, Xining, Qinghai, 810005, China
Abstract
The evolution of oxide inclusions and cleanliness control in Al-killed GCr15SiMn bearing steel was investigated using a combination of industrial tests and thermodynamic calculations during the secondary refining process. Three different refining conditions were employed in the LF process. With varying ranges of slag basicity (about 5.6–5.7, 4.8–4.9 and 3.9–4.3) and Al content (0.028–0.035 mass%, 0.023–0.025 mass% and 0.014–0.02 mass%), the total oxygen content in the steel after VD refining was measured as 0.0019 mass%, 0.0017 mass% and 0.0008 mass%, respectively. Throughout the refining process, the inclusions underwent a transformation from MgO-Al2O3 (or Al2O3) into CaO-Al2O3(-MgO), and eventually to CaO-Al2O3-SiO2 inclusions. Furthermore, it was observed that under high Al content and slag basicity refining conditions, a significant number of inclusions in VD treatment were formed and transformed into CaO·Al2O3·SiO2 inclusions enriched with 60 mass% CaO. This indicated that when the proportion of CaO in calcium aluminates exceeded 45 mass%, there was an increased risk of larger-sized inclusions. Conversely, refining conditions with a slag basicity of 3.9–4.3 and an Al content of 0.014–0.02 mass% demonstrated effective inclusion control, resulting in lower number density, smaller sizes within 10 μm and an average composition located in the liquid region. This study carries important practical significance for the smelting of high cleanliness GCr15SiMn bearing steel.