An Electron Spin Resonance Study of the Copper (II) Interaction with Wool-Keratin

Author:

Kokot S.1,Feughelman M.1,Golding R.M.2

Affiliation:

1. School of Textile Technology, University of New South Wales, P. O. Box 1, Kensington, 2033, New South Wales, Australia

2. School of Chemistry, University of New South Wales, P. O. Box 1, Kensington, 2033, New South Wales, Australia

Abstract

An examination of the Cu (II)/wool esr signal intensity variations, together with other relevant copper (II) uptake data, have shown that two types of products are formed during the Cu (II)/wool interaction. One of these gives rise to the observed esr signal, while the other is a diamagnetic sulfide of copper. The latter product arises as a result of a reaction of the metal ion and the products of a water/wool interaction. A reaction scheme consistent with the experi mental observations is suggested.

Publisher

SAGE Publications

Subject

Polymers and Plastics,Chemical Engineering (miscellaneous)

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