New class of magenta dyestuffs based on azomethine pyrazolone disperse dyes: Synthesis, characterization, and dyeing performance on polyester fabrics with ultraviolet protection and pH-dependent properties

Abstract

Eight azomethine pyrazolone magenta dyes with iminodiethanol groups have been synthesized from 1,3-disubstituted- 1H-pyrazol-5( 4H)-ones in good yield. The newly synthesized dyes were characterized using spectroscopic data and elemental analyses techniques. All dyes have been successfully applied to polyester fabrics as disperse dyes where their dyeing performances have been discussed and evaluated in detail. The shades of these dyes ranged from red violet, purple and dark purple colors with good depth, brightness and good leveling properties. Multifunctional properties such as color representation, colorimetric data (L*, a*, b*, C*, h*, K/S), fastness properties of the dyed samples with respect to washing, perspiration, rubbing and light fastness have been discussed and evaluated in detail. The degree of exhaustion and fixation was also achieved after establishing the optimal dyeing conditions at 130°C, high pressure, 2% shade, and pH ≈5. As well, the influence of the dye bath pH on the K/S percentage and color intensity was estimated and discussed. Furthermore, the dyed fabrics were tested for ultraviolet protection factor and the results showed that these dyes gave excellent ultraviolet protection.