The Preparation of Partially Cyanoethylated Cotton with Acrylonitrile-Reference-Cited by-同舟云学术

The Preparation of Partially Cyanoethylated Cotton with Acrylonitrile

Published:1955-03 Issue:3 Volume:25 Page:246-253
ISSN:0040-5175
Container-title:Textile Research Journal
language:en
Short-container-title:Textile Research Journal

Author:

Daul George C.¹,Reinhardt Robert M.¹,Reid J. David¹

Affiliation:

1. Southern Regional Research Laboratory, New Orleans, Louisiana

Abstract

The preparation of partially cyanoethylated cotton with acrylonitrile in the presence of sodium hydroxide is described, including effects of changes in time, temperature, and concentration of reagents. Products with retention of the fibrous form have been ob tained with degrees of substitution up to 2.7 cyanoethyl groups per anhydroglucose unit. Hydrolysis of the cyanoethyl group occurs readily under alkaline conditions and re sults in both cleavage and conversion to the carboxyethyl group. Maximum conversion in the latter case was 29%.

Publisher

SAGE Publications

Subject

Polymers and Plastics,Chemical Engineering (miscellaneous)

Link

http://journals.sagepub.com/doi/pdf/10.1177/004051755502500308

Reference17 articles.

1. American Cyanamid Co., Synthetic Organic Chemicals Department. "Cyanamid's Nitrogen Chemicals Digest: The Chemistry of Acrylonitrile," pp. 20, 71-74, New York (1951).

2. Anon., Manufacturing Chemists' Assoc., Chem. Safety Data Sheet SD-31, 17 pp. (1949).

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