Study of relaxation behavior and processability of polybutadiene rubber composition-Reference-Cited by-同舟云学术

Study of relaxation behavior and processability of polybutadiene rubber composition

Published:2019-01-07 Issue:7-8 Volume:51 Page:727-739
ISSN:0095-2443
Container-title:Journal of Elastomers & Plastics
language:en
Short-container-title:Journal of Elastomers & Plastics

Author:

Nandi Sangita¹,Subbaiah Yogesha¹,Manchana Ravinath¹,Mitra Susanta¹

Affiliation:

1. SABIC Technology Center, Bengaluru, Karnataka, India

Abstract

In this work, nickel-catalyzed high- cis 1,4-polybutadiene rubbers (PBR) with different molecular weight, molecular weight distribution, and Mooney relaxation time have been solution blended at different ratios and their rheological, thermal, and physical properties were characterized. PBR blend compositions showed similar processability as pristine rubber grades at higher temperature, but their Mooney relaxation time and rheological branching index (BI) are distinctly different from both pristine PBR grades at low temperature. In addition, Mooney relaxation time and BI of the blends were found to be independent of blend compositions; however, glass transition temperature ( Tg), cis%, volatile% of the compositions remain similar to the raw rubbers.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1177/0095244318822071

Reference24 articles.

1. Influence of submicron tiny gel rubber particles on the estimation of grafting and rubber efficiency in high-impact polystyrene

2. Jang YC, Kwag GH, Yoon D, et al. Process for controlling the molecular weight distribution of high 1,4-cis polybutadiene. Patent US6013746A, USA, 1999.

3. Wieder W, Kuhlmann D, Nentwig W. Process for producing diene rubbers polymerized by means of Nd catalysts and exhibiting reduced cold flow and low intrinsic odor. Patent US5567784A, USA, 1995.

4. Pettey CC, Hartsock DL, Zhou JJ. Cold flow resistant compositions containing rubber and a block copolymer. Patent US20130303696A1, USA, 2013.

5. Halasa AF, Hsu WL. Technique for reducing the cold flow of rubbers. Patent EP0884360A1, EP, 1998.

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Study on the nonlinear viscoelastic behavior of rubber composites filled with silica;Alexandria Engineering Journal;2024-06

2. Influence of high temperature GPC/SEC detection modes on the accurate molar mass estimation of slurry phase multimodal HDPE reactor materials;Journal of Elastomers & Plastics;2022-12-06