Fluorescent electrospun polyvinyl alcohol/CdSe@ZnS nanocomposite fibers

Author:

Atabey Emre1,Wei Suying2,Zhang Xi1,Gu Hongbo13,Yan Xingru1,Huang Yudong3,Shao Lu3,He Qingliang1,Zhu Jiahua1,Sun Luyi4,Kucknoor Ashwini S5,Wang Andrew6,Guo Zhanhu1

Affiliation:

1. Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX77710, USA

2. Department of Chemistry and Biochemistry, Lamar University, Beaumont, TX77710, USA

3. School of Chemical Engineering and Technology, Harbin Institute of Technology, 150001China

4. Department of Chemistry and Biochemistry, Texas State University-San Marcos, San Marcos, TX, 78666, USA

5. Department of Biology, Lamar University, Beaumont, TX77710, USA

6. Ocean NanoTech, LLC, 2143 Worth Ln., Springdale, AR72764, USA

Abstract

Uniform and bead-free polyvinyl alcohol (PVA) and its nanocomposite fibers filled with different loadings of CdSe@ZnS quantum dots (QDs) were prepared by the electrospinning process. The incorporation of QDs into PVA solution lowered the viscosity of the system. The electrospinning parameters, including applied voltage, feed rate, and working distance were optimized to prepare high quality nanocomposite fibers. Increasing the voltage from 20 to 25 kV, the average diameter of PVA fibers reduced from ca. 284 to 164 nm (42.5% decrease) and the average diameter of PVA/QDs nanocomposite fibers decreased from ca. 365 to 240 nm (34.2% decrease). The PVA/QDs (5.0 wt%) nanocomposite fibers were examined under a fluorescent microscopy. The thermal stability was investigated by both thermogravimetric analysis and differential scanning calorimetry. Fourier transform infrared spectroscopy was utilized to characterize the functionality of the fibers and to investigate the interaction between PVA and inorganic additions. Unique fluorescent phenomenon was observed in the PVA fibers after incorporation of small amount of QDs.

Publisher

SAGE Publications

Subject

Materials Chemistry,Mechanical Engineering,Mechanics of Materials,Ceramics and Composites

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