Microwave application as an alternative method to increase the efficiency of PtC catalyst in PEMFCs

Author:

Şahin Ömer1,Yilmaz Adem2ORCID,Ekinci Arzu3

Affiliation:

1. Istanbul Technical University, Department of Chemical Engineering, Faculty of Chemical and Metallurgical Engineering, İstanbul, Turkey

2. Faculty of Technology, Department of Energy Systems Engineering, Batman University, Batman, Turkey

3. Faculty of Health Sciences, Department of Occupational Health and Safety, Siirt University, Siirt, Turkey

Abstract

This study aims to develop a high-performance Pt/C catalyst for the cathode and anode parts of a modified Proton exchange membrane (PEM) fuel cell in nitrogen and argon gases at different microwave radiation powers. The pure and modified forms of the synthesized Pt/C catalysts were characterised using X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD results revealed that the crystal structure of the modified Pt/C catalyst was perfect and that the particle size of the catalytic material grew significantly as a consequence of the modification. Furthermore, the durability of PEM fuel cell electrocatalysts was investigated using the cyclic voltammetry (CV) technique. The experimental results indicated that microwave radiation had a significant effect on the particle size of the Pt/C catalyst. Additionally, the modified Pt/C catalyst exhibited a decreased activation potential loss and increased the cathode and anode power density values by 34% and 47%, respectively, compared to the Pt/C catalyst.

Publisher

SAGE Publications

Subject

Mechanical Engineering,Energy Engineering and Power Technology

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