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Fire Smart DDE Polymers

Published:2007-06 Issue:3 Volume:19 Page:323-355
ISSN:0954-0083
Container-title:High Performance Polymers
language:en
Short-container-title:High Performance Polymers

Author:

Lyon Richard E.¹,Speitel Louise²,Filipczak Robert²,Walters Richard N.²,Crowley Sean²,Stoliarov Stanislav I.³,Castelli Lauren⁴,Ramirez Michael⁵

Affiliation:

1. Airport and Aircraft Safety R&D Division, Federal Aviation Administration, William J. Hughes Technical Center, Atlantic City International Airport, NJ 08405, USA,

2. Airport and Aircraft Safety R&D Division, Federal Aviation Administration, William J. Hughes Technical Center, Atlantic City International Airport, NJ 08405, USA

3. SRA International, Egg Harbor Township, NJ 08234, USA

4. Lonza Inc., Allendale, NJ 07401, USA

5. Hewlett Packard Corporation, Aguadilla, PR 00605, Puerto Rico

Abstract

The chemistry and properties of polymers containing the “fire smart” moiety 1,1-dichloro-2,2-diphenylethene (DDE) are described. These polymers are typically derived from the bisphenol of chloral (bisphenol-C/BPC) and are low cost, easily processed, and have good mechanical properties and toughness under normal conditions. Under fire conditions, the DDE group undergoes an intramolecular rearrangement with the elimination of hydrogen chloride (a noncombustible gas) and intermolecular crosslinking to form an aromatic char residue in high yield. The flammability and mechanical properties of DDE-containing polymers are described.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1177/0954008306073720

Reference64 articles.

1. Lyon, R.E. (2000). Solid State Thermochemistry of Flaming Combustion , In: Grand, A.F and Wilkie, C.A. (eds), Fire Retardancy of Polymeric Materials, Marcel Dekker, Inc., New York, pp. 391—447.

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