Effect of polymers chemical structure on the membrane characteristics

Author:

Ronova Inga A1,Kryuchkova Svetlana V2,Yablokova Marina Y2,Alentiev Alexander Y3,Gasanova Lyudmila G2,Buzin Mikaihl I1,Kepman Aleksey V2

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds, Moscow, Russia

2. MV Lomonosov Moscow State University, Chemistry Department, Moscow, Russia

3. Topchiev Institute of Petrochemical Synthesis, Moscow, Russia

Abstract

The comparative analysis of gas transport properties and conformational parameters of membranes obtained from two polyimides and polysulfone was made. It was shown that the introduction of a sulfone group instead of a methylene group in the amine component of polyimide leads to an increase in glass transition temperature and of polymer membrane permeability coefficient and a reduction in selectivity. Also it was demonstrated that the solvent used during the preparation of polymer membranes had a significant influence on their gas transport characteristics.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Reference25 articles.

1. Ohya H, Kudryavtsev VV, Semenova SI. Polyimide membranes: appliications, fabrications, and properties. Kodansha: Gordon and Breach Pub, 1996, p. 314.

2. Relation between Gas Permeabilities and Structure of Polyimides

3. Gas permeation and separation properties of sulfonated polyimide membranes

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