Mechanistic Aspects of Polynaphthalimide Synthesis from NMR Analysis-Reference-Cited by-同舟云学术

Mechanistic Aspects of Polynaphthalimide Synthesis from NMR Analysis

Published:2009-09-16 Issue:5 Volume:21 Page:624-632
ISSN:0954-0083
Container-title:High Performance Polymers
language:en
Short-container-title:High Performance Polymers

Author:

Piroux Fabienne¹,Mercier Regis²,Picq Dominique¹

Affiliation:

1. Laboratoire des Matériaux Organiques à Propriétés Spécifiques, UMR 5041, CNRS/Université de Savoie, chemin du canal, 69360 Solaize, France

2. Laboratoire des Matériaux Organiques à Propriétés Spécifiques, UMR 5041, CNRS/Université de Savoie, chemin du canal, 69360 Solaize, France,

Abstract

The mechanism of the polycondensation reaction leading to naphthalimide polymers has been investigated using a model compound. In complement to 19F-NMR analysis, 1H- and 13C-NMR spectroscopies were used to identify the intermediate compound. It was concluded that there was no evidence for the formation of an isoimide, but the formation of an amide—acid intermediate was clearly demonstrated.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1177/0954008309339948

Reference14 articles.

1. Rusanov, A.L. and Bulycheva, E.G. (1991). Polyimides and Other High-Temperature Polymers, Elsevier, Amsterdam, p. 125.

2. Soluble sulfonated naphthalenic polyimides as materials for proton exchange membranes

3. Investigation of polyimides containing naphthalene units. II. Model compounds synthesis

Cited by 5 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Two‐step route polycondensation for polynaphthalimides synthesis through high molar mass soluble precursors: A kinetic study;Journal of Applied Polymer Science;2020-03-19

2. A theoretical investigation on the aminolysis of pyromellitic and 1,4,5,8-naphthalenetetracarboxylic dianhydrides;Computational and Theoretical Chemistry;2019-01

3. The fluorescence decay times and quantum efficiencies of 1,4,5,8-naphthalisoimides;Journal of Luminescence;2015-02

4. Photoluminescence properties of polynaphthalisoimides and polynapththalimides in solutions and thin layers;SPIE Proceedings;2011-09-09

5. Determination of the second-order 1H NMR parameters for the aromatic protons in 4-fluoroaniline and application to the analysis of the 1H NMR spectra for the aromatic protons in N4-(4′-fluorophenyl)succinamic acid and in N4-(4′-fluorophenyl)-3,3-difluorosuccinamic acid;Journal of Fluorine Chemistry;2011-04