Low-Tg polyimides containing multiple ether linkages and cyano pendants

Author:

Zhang Li1,Wu Xian2,Liu Shanyou1,Peng Jinwu1,Liu Baijun1

Affiliation:

1. National & Local Joint Engineering Laboratory for Synthesis Technology of High Performance Polymers, Key Laboratory of High Performance Plastics, Ministry of Education, College of Chemistry, Jilin University, Changchun, People’s Republic of China

2. College of Materials Science and Engineering, Jilin University, Changchun, People’s Republic of China

Abstract

Some multi-ether linked polyimides (PIs) derived from two diamine monomers containing various amount of cyano groups are synthesized by a typical two-step polymerization. Meanwhile, the PIs with similar chemical structure but without cyano groups are prepared as counterparts for comparison purposes. The obtained PIs exhibit low glass transition temperature values of 211–258°C, which are associated with their multi-ether chemical structure. Furthermore, these PIs have high thermal stability, and the temperatures at 10% weight loss are in the range of 524–616°C under nitrogen atmosphere. It is found that the introduction of cyano groups would have a great influence on the properties of the PIs. The tensile strength and Young’s modulus of one cyano-containing PI reach 121 MPa and 1.4 GPa, respectively, which are much higher than those cyano-free ones. In addition, the cyano-containing PIs exhibit different behaviors of dielectricity and solubility in comparison with the corresponding cyano-free counterparts.

Funder

National Natural Science Foundation-China

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3