Aliphatic/Aromatic Hybrid Polymers for Functionally Graded Radiation Shielding

Author:

Hu Lucy Y.,Yang Sha,Miller Adriane K.,Park Chang S.,Plichta Kristin A.,Rochford Stephanie J.,Schulz Meghan E.1,Orwoll Robert A.2,Jensen Brian J.3

Affiliation:

1. Department of Chemistry, College of William and Mary, Williamsburg, VA 23187, USA

2. Department of Chemistry, College of William and Mary, Williamsburg, VA 23187, USA;

3. NASA Langley Research Center, Hampton, VA 23681, USA

Abstract

High hydrogen-content aliphatic polymers have been identified as good for shielding against galactic cosmic radiation. However, their utility in structural elements is limited to modest temperatures where desirable mechanical properties are maintained. On the other hand, aromatic polymers generally have a broader range of operating temperatures but are less effective as radiation shields. The radiation shielding properties of aromatic polymers is enhanced by the incorporation of hydrogen-rich aliphatic groups appended to aromatic units in the macromolecular structure. It is envisioned that functionally graded polymer structures using aliphatic/aromatic hybrids can be used to meet the requirements of the service environment with beneficial radiation shielding properties in future space structural applications. This paper discusses the syntheses of such hybrid polymers.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Reference11 articles.

1. Wilson J W , Cucinotta F A , Thibeault S A , Kim M-H , Shinn J L and Badavi F F 1997 In Shielding Strategies for Human Space Exploration J W Wilson , J M , A Konradi , and F A Cucinotta , eds, NASA Conference Publication 3360 ( Hampton, VA: NASA Langley Research Center ) pp 109–149.

2. Benchmark Studies of the Effectiveness of Structural and Internal Materials as Radiation Shielding for the International Space Station

3. Synthesis and characterization of new soluble polyimides derived from 2,2-bis[3,5-dimethyl-4-(4-aminophenoxy)phenyl]propane

4. Organo-soluble polyimide (TBAPP–OPDA)/clay nanocomposite materials with advanced anticorrosive properties prepared from solution dispersion technique

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