New Poly(arylene ether sulfone)s Containing Phenolphthalein and Fluorene Moieties in the Main Chain-Reference-Cited by-同舟云学术

New Poly(arylene ether sulfone)s Containing Phenolphthalein and Fluorene Moieties in the Main Chain

Published:2010-03-29 Issue:6 Volume:22 Page:666-681
ISSN:0954-0083
Container-title:High Performance Polymers
language:en
Short-container-title:High Performance Polymers

Author:

Ciobanu Manuela¹,Cozan Vasile²,Bruma Maria¹,Begunov Roman S.³,Rusanov Alexander L.⁴,Belomoina Nataliya M.⁴

Affiliation:

1. "Petru Poni" Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, Iasi 700487, Romania

2. "Petru Poni" Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41A, Iasi 700487, Romania,

3. Yaroslavl State University, Sovetskaya Str. 14, Yaroslavl 150000, Russia

4. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Vavilov str. 28, 119991, Moscow, Russia

Abstract

New poly(arylene ether sulfone)s have been synthesized by solution polycondensation reaction of 2,4-bis[(4-chlorophenyl)sulfonyl]-1-(phenylthio)benzene)] with 4,4'-(9-fluorenylidene) bisphenol (FBP) and phenolphthalein (PP). The chemical structure of the polymers was confirmed by using both spectroscopical (FTIR, 1H-NMR) and elemental analysis methods. All the polymers were soluble in aprotic dipolar solvents. The thermal properties were investigated by differential scanning calorimetry and thermogravimetric analysis, and they, were discussed in connection with the chemical structure of the polymers. The investigation of optical properties by photoluminescence spectroscopy revealed that all the polymers displayed one emission peak in the blue domain beetwen 449 and 460 nm.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1177/0954008309354130

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