Innovative approach for the synthesis of benzoxazine-modified montmorillonite-Reference-Cited by-同舟云学术

Innovative approach for the synthesis of benzoxazine-modified montmorillonite

Published:2015-07-06 Issue:5 Volume:27 Page:599-606
ISSN:0954-0083
Container-title:High Performance Polymers
language:en
Short-container-title:High Performance Polymers

Author:

Andronescu C.¹²,Garea S. A.²,Nicolescu A.³,Deleanu C.³⁴,Eugeniu V.⁵,Iovu H.²⁶

Affiliation:

1. Department of Bioresources and Polymer Science, University “Politehnica” of Bucharest, Bucharest, Romania

2. Advanced Polymer Materials Group, University “Politehnica” of Bucharest, Bucharest, Romania

3. “PetruPoni” Institute of Macromolecular Chemistry, Iasi, Romania

4. Institute of Organic Chemistry, Romanian Academy, Bucharest, Romania

5. Department of Oxide Materials Science and Engineering, University “Politehnica” of Bucharest, Bucharest, Romania

6. Academy of Romanian Scientists, Bucharest, Romania

Abstract

The synthesis of a benzoxazine (BZ) monomer inside the montmorillonite (MT) layers was done using a diamino-modified MT as the amine component, phenol, and formaldehyde. The formation of the BZ rings within the MT layers was investigated by thermogravimetric analysis, X-ray photoelectron spectroscopy, proton nuclear magnetic resonance spectroscopy, and X-ray diffraction, this being enhanced when dioxane was used as the solvent. The morphology of the hybrid BZ monomer was investigated by scanning electron microscopy.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

Link

http://journals.sagepub.com/doi/pdf/10.1177/0954008315584170

Reference18 articles.

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