Synthesis and characterization of ternary copolyimides derived from aromatic dianhydride and aromatic diisocyanates

Abstract

A series of polyimide (PI) copolymers were synthesized via a one-step polycondensation procedure from benzophenone-3,3′,4,4′-tetracarboxylic acid dianhydride, toluene diisocyanate (TDI), and 4,4′-methylene bis(phenyl isocyanate) (MDI) with various mole ratios of TDI and MDI ranging from 70:30 to 100:0. The inherent viscosities of the resulting PIs were in the range of 0.51–0.80 dL g−1. The prepared PIs showed good solubility in common organic as well as in less polar solvents. All copolymers afforded tough and flexible films that had good thermal stability with glass transition temperature of 308–325°C and the temperatures of 5% weight loss in air and nitrogen being 420 and 460°C, respectively. The resultant PI films with thickness about 15 μm exhibited high transparency (>88%) in visible region (400–700 nm). Also, the cured PI films possessed good mechanical properties with tensile strength of 60.52–69.31 MPa and tensile modulus of 0.98–1.30 GPa.