Synthesis and properties of polyimides having a hexaphenylbenzene unit

Author:

Nabeshima Syuta1,Morikawa Atsushi1

Affiliation:

1. Department of Biomolecular Functional Engineering, Ibaraki University, Hitachi, Ibaraki, Japan

Abstract

Aromatic polyimides (PIs) with a hexaphenylbenzene unit were synthesized from 1,4-bis[4-(4-aminophenoxy)phenyl]-2,3,5,6-tetraphenylbenzene (1) and various tetracarboxylic dianhydrides by a conventional two-step procedure that included ring-opening polymerization in N-methyl-2-pyrrolidone and subsequent thermal cyclic dehydration. The PIs were characterized by X-ray diffraction, differential scanning calorimetry, thermogravimetry, and dynamic mechanical analysis. The PIs had glass transition temperatures in the range of 289–352°C, and all the polymers were amorphous. The structure–property relationships of these PIs were examined and compared with those of the previously prepared analogous PIs from 4,4′-bis(4-aminophenoxy)biphenyl (2) and 4,4′-bis(4-amino-2-phenylphenoxy)biphenyl (3). Water absorption and dielectric constants of the PIs were also compared and discussed on the basis of imide content per repeating unit.

Publisher

SAGE Publications

Subject

Materials Chemistry,Organic Chemistry,Polymers and Plastics

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