Experimental investigations of catalytic effect of Cu2+ during anodic dissolution of iron in NaCl electrolyte

Author:

Upadhyay Ritesh Kumar1,Kumar Arbind2,Srivastava Prem Kumar3

Affiliation:

1. Department of Mechanical Engineering, Birla Institute of Technology Mesra, Deoghar Campus, Jasidih, India

2. Department of Mechanical Engineering, Birla Institute of Technology Mesra, Ranchi, India

3. Department of Applied Chemistry, Birla Institute of Technology Mesra, Deoghar Campus, Jasidih, India

Abstract

Taguchi’s L9 orthogonal array has been effectively used to study the effect of process parameters such as voltage, feed rate and electrolyte concentration on material removal rate in context of two different types of electrolyte, namely, aqueous NaCl solution and CuSO4 mixed aqueous NaCl solution. The results indicated that Cu2+ ions formed due to electrochemical reactions prevent the oxidation of Fe2+ to Fe3+ and catalyze the anodic dissolution of iron during machining. The experimental results were analyzed using analysis of variance method to investigate the significance and percentage contribution of individual process parameters on performance characteristics.

Publisher

SAGE Publications

Subject

Industrial and Manufacturing Engineering,Mechanical Engineering

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