Recent Findings On the Formation and Decomposition of PCDD/PCDF in Municipal Solid Waste Incineration-Reference-Cited by-同舟云学术

Recent Findings On the Formation and Decomposition of PCDD/PCDF in Municipal Solid Waste Incineration

Published:1987-01 Issue:1 Volume:5 Page:285-294
ISSN:0734-242X
Container-title:Waste Management & Research: The Journal for a Sustainable Circular Economy
language:en
Short-container-title:Waste Manag Res

Author:

Vogg H.¹,Metzger M.¹,Stieglitz L.¹

Affiliation:

1. Nuclear Research Center Karlsruhe, Post Box 3640, D-7500, Karlsruhe, F.R.G.

Abstract

The thermal formation of PCDD/PCDF in fly ashes of refuse incineration plants preferably in the low-temperature region of the boiler at 300°C is fully confirmed. Important parameters for the reaction of formation are the oxygen content and the water vapor in the offgas. Elemental carbon in the fly ash acts as an adsorbent to the precursor compounds. The oxidation of carbon may serve as a basis for the mechanism of PCDD/PCDF formation. Both reactions proceed by the Deacon process scheme. The catalytic action of CuCl2 can be counteracted by the addition of NH3.

Publisher

SAGE Publications

Subject

Pollution,Environmental Engineering

Link

http://journals.sagepub.com/doi/pdf/10.1177/0734242X8700500140

Reference11 articles.

1. Veränderungen auf der Oberfläche eines frisch zerriebenen kristallartigen Salzes

2. Dioxin radical formation and polymerization on Cu(II)-smectite

3. Combustion, Corrosion and Fouling Aspect of Energy Recovery From Municipal Waste

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