Synthesis and characterization of a new bis-NHC palladium complex and its catalytic activity in the Mizoroki

Synthesis and characterization of a new bis-NHC palladium complex and its catalytic activity in the Mizoroki–Heck reaction

Published:2020-05-14 Issue:11-12 Volume:44 Page:684-688
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Feng Can¹^ORCID,Liu Cheng-xin¹,Wang Yu-fang²,Cui Jin³,Zhang Ming-jie¹

Affiliation:

1. Department of Chemistry, School of Sciences, Tianjin University, Tianjin, P.R. China

2. Scientific Research Department, Shijiazhuang University of Applied Technology, Shijiazhuang, P.R. China

3. National Foodstuff Inspection Center, Tianjin Product Quality Inspection Technology Research Institute, Tianjin, P.R. China

Abstract

A new bis- N-heterocyclic carbene palladium complex, (C13H9N2F2)2PdCl2, is synthesized by a three-step reaction and characterized by 1H NMR and 13C NMR spectroscopy as well as by X-ray crystallography. This new bis- N-heterocyclic carbene palladium complex has excellent stability and is capable of efficiently catalyzing the Mizoroki–Heck coupling reaction of aryl halides with acrylates.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.1177/1747519820917883

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