Affiliation:
1. Key Laboratory of Theoretical Organic Chemistry and Functional Molecule of Ministry of Education, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, P.R. China
Abstract
For the first time, using PCl3, a range of tert-butyl esters is chlorinated successfully, allowing access of both aromatic acid chlorides and aliphatic acid chlorides in good yields. The method features simple reaction conditions and wide substrate scope. Various tert-butyl esters including aryl esters, alkenyl esters, and alkyl esters were tolerated well in the reaction. A plausible mechanism is proposed.
Funder
Natural Science Foundation of Hunan Province
Open Project Program of Key Laboratory of Theoretical Organic Chemistry and Functional Molecule, Ministry of Education
National Natural Science Foundation of China
Cited by
7 articles.
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