A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis-Reference-Cited by-同舟云学术

A rhenium(I) complex which reacts with aldehydes and ketones in aqueous media: A structural, spectroscopic and theoretical analysis

Published:2020-05-19 Issue:11-12 Volume:44 Page:733-737
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Harding Lindsay P¹,McRobbie Asuka AT¹,Riis-Johannessen T²,Pope Simon JA³,Rice Craig R¹,Rollinson Donna¹,Whitehead Martina¹^ORCID

Affiliation:

1. Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield, UK

2. School of Chemistry, Cantock’s Close, University of Bristol, Bristol, UK

3. School of Chemistry, Cardiff University, Cardiff, UK

Abstract

A Re(I) complex of 3,3′-diamino-2,2′-bipyridine reacts irreversibly with aldehydes and unhindered ketones in water to form bis-aminal cyclised derivatives with the solid-state structure of the reaction with benzaldehyde reported. This reaction produces a Re(I) complex which is significantly more emissive than the starting compound.

Funder

Engineering and Physical Sciences Research Council

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.1177/1747519820917888

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