Affiliation:
1. College of Chemistry and Chemical Engineering, Jinzhong University, Jinzhong, P.R. China
Abstract
A new coordination framework {[Mn7(L)4(OH)2(H2O)4(DMA)4]·8H2O·6DMA}n (H3 L = 3,3′,3″-[1,3,5-benzenetriyltris(carbonylimino)]tris(benzoate); DMA = N,N-dimethylacetamide) is synthesized under mixed solvothermal conditions. Structural analysis reveals that this complex possesses a three-dimensional framework with (3,10)- c topology based on different [Mn6] clusters. Moreover, magnetic investigations suggest that intra-cluster Mn(II) ions exhibit antiferromagnetic coupling.
Funder
jinzhong university
Shanxi “1331 Project” Key Innovative Research Team
Technological Innovation Programs of Higher Education Institutions in Shanxi