1,3,4-Oxadiazole derivative: Photophysical, gelation, self-assembly, and Fe3+ fluorescence sensing properties

Author:

Zhang Tianren12ORCID,Jiang Sitong1,Wang Guizhi1,Zuo Youpeng1,Yu Shuwen1,Zhang Qing1,Hu Xueqing13

Affiliation:

1. Key Laboratory of Spin Electron and Nanomaterials of Anhui Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou, China

2. Key Laboratory of Automobile Materials, Ministry of Education, College of Materials Science and Engineering, Jilin University, Changchun, China

3. Department of Nephrology, the Affiliated Huaihai Hospital of Xuzhou Medical University, Xuzhou, China

Abstract

A new 1,3,4-oxadiazole derivative (BPOXD-B8) was synthesized. The emission properties of BPOXD-B8 in different solutions were studied. BPOXD-B8 could form organogels in different solvents, especially in methanol. The gelation and self-assembly properties of BPOXD-B8 were investigated by SEM, X-ray diffraction (XRD), temperature-dependent FTIR, and UV-vis. The main driving forces during self-assembly are π–π interaction and the van der Waals force. In addition, the BPOXD-B8 solution showed fluorescence sensing properties for Fe3+ ions. BPOXD-B8 with a relatively low detection limit (0.079 μM) and relatively small standard deviations (<5%) indicate that the present system is indeed suitable for real-life sample analysis.

Funder

suzhou university

national natural science foundation of china

Excellent Youth Research Project of Anhui Province

scientific research and sharing platform construction project of shaanxi province

university natural science research project of anhui province

natural science foundation of anhui province

the Medical Science and Technology Innovation Project of Xuzhou Municipal Health Commission

Publisher

SAGE Publications

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