Synthesis, characterization, thermal behavior, and antitumor activities of an Ag(I) complex based on 4-(2-hydroxyphenyl)-2-methylpyrimidine

Author:

Li Wu-Wu1ORCID,Zheng Min-Yan1,Shang Yong-Hui1,Xu Jin-Qiong1,Zhang Zun-Ting2,Zheng Hao-Nan1,Li Xiao-Peng1,Weng A-Tong1,Feng Ling-Ying1,Liu Lu1

Affiliation:

1. College of Chemistry & Chemical Engineering, Xianyang Normal University, Xianyang, P.R. China

2. Key Laboratory of the Ministry of Education for Medicinal Resources and Natural Pharmaceutical Chemistry, National Engineering Laboratory for Resource Development of Endangered Crude Drugs in Northwest of China and School of Chemistry and Chemical Engineering, Shaanxi Normal University, Xi’an, P.R. China

Abstract

A new Ag(I) coordination complex, Ag(C11H10N2O)2·NO3 (C11H10N2O = 4-(2-hydroxyphenyl)-2-methylpyrimidine) is successfully synthesized and characterized by infrared spectroscopy, elemental analysis, and single-crystal X-ray diffraction analysis. This complex features a three-dimensional framework consisting of hydrogen bonds, π–π stacking interactions, coordination interactions, and electrostatic interactions. Moreover, the thermal stability and non-isothermal thermal decomposition reaction kinetics of the complex are well investigated by the methods of Kissinger and Ozawa. Finally, the antitumor ability of the complex is evaluated against human lung cancer cells (NCI-H460), human hepatocellular cancer cells (HepG2), and human breast cancer cells (MCF7). The complex exhibits potent antitumor activities against HepG2 and MCF7 cancer cells.

Funder

natural science basic research program of shaanxi province

xianyang normal university

University Students Research and Innovation Training Program of Ministry of Education

natural science foundation of shaanxi provincial department of education

Publisher

SAGE Publications

Subject

General Chemistry

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