Effect of agro-waste-derived graphene/titanium powders on polyester resin for supercapacitor electrodes

Author:

Livinus Okeke Chibuike1,Maduabuchi Chika23,Uyor Uwa Orji14,Sunday Aigbodion Victor145

Affiliation:

1. Department of Metallurgical and Materials Engineering, University of Nigeria, Nsukka, Nigeria

2. Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA, USA

3. Artificial Intelligence Laboratory, University of Nigeria Nsukka, Nsukka, Enugu State, Nigeria

4. Africa Centre of Excellency for Sustainable Power and Energy Development, University of Nigeria, Nsukka, Nigeria

5. Faculty of Engineering and the Built Environment, University of Johannesburg, Johannesburg, South Africa

Abstract

Polyesters are renowned for their chemical resistance and thermal/mechanical properties but lack electrical conductivity. This study reinforces polyester with titanium and varying graphene (derived from rice husk ash [RHA]) percentages, testing resultant nanocomposites as supercapacitor electrodes. Transmission electron microscope (TEM), scanning electron microscope (SEM) and X-ray diffraction (XRD) confirm successful graphene synthesis from RHA, polymer crystallinity change and GN/Ti particle dispersion. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) assess nanocomposites, revealing enhanced properties with graphene. Suitability for supercapacitor electrodes increases proportionally with higher graphene percentages in CV tests. At a 20-mV/s scan rate, the specific capacitance for P–25 wt-%G sees an impressive 614% increase, underscoring significant enhancement in polyester matrix properties.

Publisher

SAGE Publications

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