Effects of phosphorus-free antioxidants on oxidation stability and high-temperature tribological properties of lubricants

Author:

Liping Wang12,Dongya Zhang3,Hongxing Wu1,Youbai Xie1,Guangneng Dong1

Affiliation:

1. Key Laboratory of Education Ministry for Modern Design & Rotor-Bearing System, Xi'an Jiaotong University, Xi'an, People's Republic of China

2. Petro China Lanzhou Lubricating Oil R & D Institute, Lanzhou, People's Republic of China

3. School of Mechanical and Precision Instrument Engineering, Xi'an University of Technology, Xi'an, People's Republic of China

Abstract

Oxidation stability plays an important role on the engine oil service performance. In this paper, the phosphorus-free antioxidants of diphenylamine, hindered phenol and dibutyldithiocarbamate, combined with zinc dialkyldithiophosphate were added as antioxidants in the base oil and the fully formulated 5W-30 oil, and the oxidation stabilities were evaluated by pressurized differential scanning calorimetry and Romaszewski oil bench oxidation standard tests. Meanwhile, the tribological properties of the fresh and aged oils were evaluated by a SRV tribo-meter. The results indicated that (i) an optimal ternary complex antioxidant of dibutyldithiocarbamate: diphenylamine: hindered phenol (ratio of 2:1:2) displayed good antioxidation property, and (ii) the fully formulated 5W-30 oil containing optimized ratio phosphorus-free antioxidants had better tribological properties than the commercial SN 5W-30 oil.

Publisher

SAGE Publications

Subject

Surfaces, Coatings and Films,Surfaces and Interfaces,Mechanical Engineering

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3