Dodecyl methacrylate (DM) dispersion-assisted surface modification approach for increasing crystallinity of coir fibers

Abstract

Coir fiber crystallinity is crucial since it widens the range of possible uses for natural fiber. To increase the crystallinity of coir fiber, the study describes an easy-to-use, simple-to-implement method that is cost-effective, eco-friendly, and highly productive. With the help of dodecyl methacrylate disperson, hydrocarbon molecules of varying chain lengths are covalently attached to the surface of coir fibers, modulating their surface wettability. There are a few different long-chain hydrocarbon compounds employed, including n-butyl methacrylate, n-octyl acrylate, and dodecyl methacrylate (DM), but DM has shown to be the most effective. The degree of grafting yield alteration is determined gravimetrically. It has been found that grafting yields of 28–30 wt.% can be used to convert hydrophilic coir fibers into water repellent crystalline fibers (water contact angle 148°). A total of 15 nm of dispersion, a disperson rate of 2 nm/min, DM concentration of 20%, and water content of 10% are fixed as key reaction parameters. Thermal and mechanical analyses show no significant changes in the fiber structure during alteration. The grafting and changes in surface wettability are well supported by the surface morphology of pure and modified coir fiber, which can be seen using scanning electron microscopy.