Study of electro-thermal properties of pyrrole polymerised knitted fabrics

Abstract

This paper presents the results of research work carried out to investigate the heating properties of nylon knitted fabric impregnated with a polymerised solution of polypyrrole. The inspection of the molecular polypyrrole electro-conductive pathways responsible for the heating effect of the knitted fabric was investigated using a scanning electron microscope. Further to this, the heat generated by the polypyrrole impregnated fabric was observed under varying power supply terminal separation distances in order to understand the relationship between the length of the polypyrrole electro-conductive fabric and the level of heat generated. The sample with the lowest terminal separation distance i.e. 5 × 1 cm2 produced more localized heat and reached a temperature level of 114℃ in less than three minutes. Additionally a thermo-mechanical characterisation of this knitted heating material was carried out against varying levels of strain and compression. The maximum stress and ultimate strain values of both treated and untreated samples were found to be similar. However, it was observed that the extensibility of the samples affected the generation of heat. The suitability of knitted fabric impregnated with polymerised polypyrrole heating elements for in-car applications where the heating elements may be next to skin was also discussed. The investigation concluded that polypyrrole heating fabric is suitable for next-to-body heating applications which can be engineered by controlling the optimum electrical pathways provided by the network of polypyrrole molecular chains together with the correct power supply levels to work under a defined fabric strain range. The purpose of the current research is to provide a new material that could help to develop heating fabrics with improved textile properties.