Study of frequency dependence properties of CCTO-BT/polymer composites

Author:

Mishra Swagatika1,Mishra Punyapriya1ORCID,Mohapatra Deepak Kumar1ORCID,Mishra Punyatoya2,Mishra Dinesh Kumar3,Shadangi Krushna Prasad4

Affiliation:

1. Department of Mechanical Engineering, Veer Surendra Sai University of Technology, Burla, Odisha, India

2. Department of Physics, Parala Maharaja Engineering College, Berhampur, Odisha, India

3. Department of Metallurgical and Materials Engineering, Veer Surendra Sai University of Technology, Burla, Odisha, India

4. Department of Chemical Engineering, Veer Surendra Sai University of Technology, Burla, Odisha, India

Abstract

In the current study, the calcium copper titanate (CCTO)/polymer, barium titanate (BT)/polymer, and CCTO-BT/polymer composites with variable volume fractions of CCTO and BT are fabricated using hand lay-up and compression molding processes. The composites are characterized for the frequency dependence on dielectric properties, conductivity, impedance spectroscopy, and electrical modulus. X-ray diffraction (XRD) patterns of CCTO-BT/polymer composite samples confirmed the presence of both CCTO and BT ceramic samples separately. The dielectric properties of hybrid CCTO-BT/polymer composites with 10 vol% CCTO 10 vol% BT, 12 vol% CCTO 8 vol% BT, and 8 vol% CCTO 12 vol% BT was found relatively better than those of the single ceramic filler reinforced polymer composites. AC conductivity analysis shows a significant improvement in the results of hybrid filler-filled CCTO-BT/polymer composites in comparison with single filler-filled polymer composites. Thus, impedance analysis confirms higher insulating properties for 8 vol% CCTO 12 vol% BT and 12 vol% CCTO 8 vol% BT hybrid CCTO-BT/polymer composites with respect to the single and other hybrid ceramic polymer composites. The analysis suggests the hybrid CCTO-BT/polymer composites to be adopted as a possible dielectric material for energy storage devices and other electronic applications.

Publisher

SAGE Publications

Subject

Mechanical Engineering

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