Botcinolide/Botcinin: Asymmetric Synthesis of the Key Fragments-Reference-Cited by-同舟云学术

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Botcinolide/Botcinin: Asymmetric Synthesis of the Key Fragments

Published:2011-04 Issue:4 Volume:6 Page:1934578X1100600
ISSN:1934-578X
Container-title:Natural Product Communications
language:en
Short-container-title:Natural Product Communications

Author:

Ramírez-Fernández Jacinto¹,Botubol José Manuel¹,Bustillo Antonio J.¹,Aleu Josefina¹,Collado Isidro G.¹,Hernández-Galán Rosario¹

Affiliation:

1. Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Cádiz, Poligono Rio San Pedro s/n, 11510 Puerto Real, Cádiz, Spain

Abstract

The asymmetric synthesis of key fragments of the phytotoxic toxins botcinolide/botcinin is reported. The synthesis of 1 and 1a are based on a convergent route via esterification and alkene metathesis of fragments A, B or C, B, which were obtained by Evans aldol condensation and stereoselective crotylation, respectively.

Publisher

SAGE Publications

Subject

Complementary and alternative medicine,Plant Science,Drug Discovery,Pharmacology,General Medicine

Link

http://journals.sagepub.com/doi/pdf/10.1177/1934578X1100600404

Reference20 articles.

1. Botcinolide: A Biologically Active Natural Product fromBotrytis cinerea

2. Structure and solution-state conformation of botcinolide, a new biologically active metabolite from the fungus Botrytis cinerea

3. Studies directed towards the synthesis of botcinolides: synthesis of the nonalactone ring of 2-epibotcinolide

4. Stereoselective Total Synthesis of the Proposed Structure of 2-Epibotcinolide

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