Epimanool and a New 2,6-Dideoxy-hexopyran-3-ulose Derivative from Celmisia viscosa-Reference-Cited by-同舟云学术

Epimanool and a New 2,6-Dideoxy-hexopyran-3-ulose Derivative from Celmisia viscosa

Published:2013-06 Issue:6 Volume:8 Page:1934578X1300800
ISSN:1934-578X
Container-title:Natural Product Communications
language:en
Short-container-title:Natural Product Communications

Author:

Sansom Catherine E.¹,Larsen Lesley¹,Evans Alison C.¹,Perry Nigel B.¹

Affiliation:

1. New Zealand Institute for Plant & Food Research Ltd, Department of Chemistry, University of Otago, Dunedin, New Zealand

Abstract

Epimanool is reported for the first time in high yield (up to 7% w/w) from the New Zealand endemic shrub Celmisia viscosa (Asteraceae), together with a new derivative, containing the first natural example of a 2,6-dideoxy-hexopyran-3-ulose. The absolute stereochemistry of epimanool was proven by conversion to manool ketone, which also showed the potential of this plant as a source of perfume starting material. Epimanool is present in the sticky exudate on the leaf surfaces of C. viscosa.

Publisher

SAGE Publications

Subject

Complementary and alternative medicine,Plant Science,Drug Discovery,Pharmacology,General Medicine

Link

http://journals.sagepub.com/doi/pdf/10.1177/1934578X1300800601

Reference25 articles.

1. Über den Diterpenalkohol aus dem Holz von Dacrydium biforme, II. Mitteil.: Die Ozonisierung von Manool

2. Diterpene Chemistry. XI. Synthesis of Perfumery Compounds from Labda-8(17),14-dien-13-ol (Manool)

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Halimane Diterpenes in the Alpine Daisy Celmisia viscosa: Absolute Configuration, 2,6-Dideoxyhexopyran-3-ulosides, Conformational Flexibility, and Intraspecific Variation;Journal of Natural Products;2022-07-26