Influence of Different Endothermic Foaming Agents on Microcellular Injection Moulded Wood Fibre Reinforced PP Composites

Abstract

Microcellular wood fibre reinforced polypropylene composites, a new development using bio-fibre strengthened plastic, were prepared in an injection moulding process. The influence of three different endothermic chemical foaming agents was examined. The effects of various concentrations (1 to 4 wt.% of the composites) of the chemical foaming agent on the properties of the composites was studied with a view to establishing the concentration-structure-property relationships for these materials. The influence of wood fibre type (hard wood and soft wood) on the microcellular structure and physico-mechanical properties of the composites was also investigated. Microcell morphology (cell size, shape and distribution) was observed using scanning electron microscope. The chemical substance of different endothermic foaming agent affected the microcellular structure of hard and soft wood fibre-PP composites. Endothermic foaming agent with chemical substance polymeric microsphere (ESC 5313) showed finer microcellular structures compared to other foaming agents and 4 wt.% content of chemical foaming agent exhibits finer microcellular structures than the other contents. The reinforcing of soft wood fibre showed significantly finer microcellular structures than the hard wood fibre reinforcements. Density reduced maximum 30% and decreased up to 0.721 g/cm3 at soft wood fibre 30 wt.% content with coupling agent maleic anhydride grafted polypropylene (MAH-PP). With the addition of MAH-PP, specific tensile strength and specific flexural strength increased maximum 60% and 55% respectively with foaming agent ESC 5313 at soft wood fibre 30 wt.% content.