Affiliation:
1. Department of Chemical Engineering, Laval University and CERMA, Quebec City, Qc, Canada, G1V 0A6
Abstract
This study investigates how the properties of a wood polymer composite are modified by recycling, especially how the presence of fibres modify polymer degradation. To this end, low density polyethylene was selected as the matrix and yellow birch fibres as the reinforcement. The effect of recycling was simulated via closed-loop reprocessing of the material up to ten times under constant extrusion conditions. For each generation, thermal, rheological and morphological measurements were combined with macromolecular investigations including the complete molecular weight distribution of the polymer. The results revealed that polymer crystallinity increased with the number of composite regeneration, while the zero-shear viscosity decreased with recycling. Elongational rheology also revealed that the behaviour of the polymer changed from strain hardening to strain softening for the composite. From the morphological analysis, a degradation severity coefficient was defined to characterize the impact of operating conditions on fibre length. Finally, macromolecular investigations showed that the number-average molecular weight (Mn) of the polymer was more affected than the weight-average molecular weight (Mw). The relative branching factor and the branching frequency were also modified by the effect of reprocessing with and without the presence of wood fibre.
Subject
Materials Chemistry,Polymers and Plastics,Organic Chemistry,General Chemical Engineering
Cited by
9 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献