Effect of Recycling on Fire Retardancy of Intumescent Polypropylene Based Blends

Author:

Almeras Xavier1,Le Bras Michel1,Hornsby Peter2,Bourbigot Serge3,Marosi Gyorgy4,Anna Peter4,Delobel René5

Affiliation:

1. Laboratoire Proccédés d'Elaborations de Revêtements Fonctionnels UPRES EA 1040, ENSC-Lille, BP 108, 59652 Villeneuve d'Ascq Cedex France

2. Brunel University, Brunel UK

3. ENSAIT, Gemtex, Roubaix, France

4. Technical University of Budapest, Budapest Hungary

5. CREPIM Bruay la Buissière, France

Abstract

This work deals with the effect of recycling on halogen-free flame retarded polypropylene blends. The intumescent ammonium polyphosphate/polyamide-6/polypropylene blend is considered. The study of the fire properties using cone calorimeter shows a decrease in the fire performance. Recycling the blends induces chemical modifications of polymer and additives. The chemical modifications due to the recycling are investigated by solid state31P NMR. It is shown that APP is degraded. These modifications induce a loss of the ammonium contents, which could explain the decrease in the fire performance.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,Organic Chemistry,General Chemical Engineering

Reference19 articles.

Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Recycling Plastics: Advantages and Limitations of Use;A Practical Guide to Plastics Sustainability;2020

2. Plastics Solutions for Practical Problems;Thermoplastics and Thermoplastic Composites;2018

3. Plastics Solutions for Practical Problems;Thermoplastics and Thermoplastic Composites;2013

4. Influence of the Recycling Process on the Fire-Retardant Properties of PP/EPR Blends;Macromolecular Materials and Engineering;2011-01-28

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