Enhanced mechanical properties of radiation vulcanized natural rubber latex by using t-butyl hydroperoxide

Author:

Varghese Neethu1ORCID,Varghese Siby1,Shybi AA1,Kurian Thomas2

Affiliation:

1. Technical Consultancy Division, Rubber Research Institute of India, Kottayam, Kerala, India

2. Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Kochi, Kerala, India

Abstract

The mechanical properties of both radiation (RVNRL) and peroxide vulcanized natural rubber latex (PVNRL) are low when compared to sulphur prevulcanized natural rubber latex (SVNRL). This paper deals with the effect of peroxide on the mechanical properties of radiation vulcanized NR latex film. Here, n-butyl acrylate (n-BA) was used as sensitizer and t-butyl hydroperoxide (t-BHPO) as co-vulcanizing agent during irradiation. It was found that the addition of t-BHPO is more practical method to reduce the vulcanization dose. Thermal ageing study showed that the best retention in tensile properties was shown by RIPV vulcanizates.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,Organic Chemistry,General Chemical Engineering

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