Multiwalled carbon nanotubes reinforced flexible blend nanocomposites membranes for pervaporation separation of aromatic-aliphatic mixtures

Author:

Thomas Saliney1,Thomas Shaji2,Kadam Sujit A3,Jose Thomasukutty4,Abraham Jiji5,George Soney C.4ORCID,Thomas Sabu6

Affiliation:

1. School of Chemical Sciences, Mahatma Gandhi University, Kottayam, India

2. Department of Chemistry, Bishop Abraham Memorial College, Pathanamthitta, India

3. Department of Physics, National Dong Hwa University, Shoufeng, Taiwan

4. Department of Basic Sciences, Centre for Nanoscience & Technology, Amal Jyothi College of Engineering, Kottayam, India

5. Department of Chemistry, Vimala College, Thrissur, India

6. International and Inter University Centre for Nano Science & Nanotechnology, Mahatma Gandhi University, Kottayam, India

Abstract

Multiwalled carbon nanotubes (MWCNT) reinforced NR-NBR blend nanocomposite membranes were prepared and potentially employed for the pervaporation separation of aliphatic – aromatic mixtures. For a 50 wt% benzene feed, the blend nanocomposite membranes had a total flux of 1.265 kgm−2h−1 and separation factor of 1.59 at room temperature. The blend membranes exhibited aromatic selectivity for the separation of aromatic – aliphatic mixtures. 2 phr MWCNT/blend nanocomposite membranes exhibited similar trend for the separation of 10 wt% feed toluene mixture. Trasmission electron microscopy (TEM) images of the blend nanocomposites revealed the well dispersion and distribution of MWCNT in the polymer matrix. The well dispersed MWCNT/blend membranes selectively separate aromatic components from aliphatic – aromatic mixtures.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,Ceramics and Composites

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