The Effect of Metal Chelates of Poly(Iminoethylene) Dithiocarbamate Copolymer Interchelated with Montmorillonite on the Fire Retardancy of Polypropylene

Author:

Nour Mohamed A.1,Gilman Jeffrey W.2

Affiliation:

1. National Institute for Standards (NIS), Tersa Street, El-Ahram, El-Giza, P.O. Box: 136 Giza, Code No. 12211, Egypt

2. Materials and Products Group, Fire Research Division, National Institute of Standards and Technology (NIST), Building 224, mail stop 8665. Office A263, 100 Bureau Drive, Gaithersburg, MD 20899-8665, USA

Abstract

The flammability properties of polypropylene (PP) were improved using metal chelates of poly(iminoethylene) dithiocarbamate copolymer intercalated with montmorillonite. These chelates were obtained from prepared intercalated Zn, Cu, Ni and Co metal chelates of poly(iminoethylene) dithiocarbamate copolymer with montmorillonite. Cone calorimetry was used to assess the flammability of the formulated PP samples. The thermal stability of the materials produced was studied using thermogravimetric analysis (TGA) and good thermal stability with high char yield was observed.

Publisher

SAGE Publications

Subject

Materials Chemistry,Polymers and Plastics,Ceramics and Composites

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