Effect of Molecular Weight of Polycarboxylate-type Superplasticizer on the Rheological Properties of Cement Pastes

Abstract

In order to study the effect of molecular weight of polycarboxylate-type superplasticizer (PC) on the rheological properties of cement pastes, PCs with different molecular weights (low, medium, high) were synthesized, and used as superplasticizers for cement suspensions. The effect of molecular weight of PC on the zeta potential, adsorption, and rheological behaviour of the corresponding cement suspensions were investigated systematically. Among the PCs, PC with a medium molecular weight always produced the lowest apparent viscosity for cement pastes at the same shear rate. Compared to PC with a low molecular weight, PC with a high molecular weight presented a stronger initial dispersing ability and a weaker dispersing stabilizing ability for cement pastes. In addition, PC with a low molecular weight had an advantage over PC with a high molecular weight for reducing the viscosity of paste in the low added dosage or low water/cement ratio, but the latter had the advantage of reducing the viscosity of the paste when the added dosage or water/cement ratio was high. This understanding of the rheological properties of cement pastes incorporating PC will provide an important reference for the application and synthesis of PC with high efficiency.